丙二醇乙醚(慢干剂)安全技术说明书
本作品内容为丙二醇乙醚(慢干剂)安全技术说明书,格式为 doc ,大小 60456 KB ,页数为 6页
('丙二醇乙醚安全技术说明书(MSDS)1.Nameofchemicalproductandnameofcompany化学产品及公司名称Nameofproduct:propyleneglycolmonoethylether(MSDS)产品名称:丙二醇乙醚Codeofproduct:P2产品代号:P2Nameofcompany:YangzhouHualunChemicalIndustryCompany,Ltd.公司名称:扬州化工有限公司Add:DinghuoTown,JiangduCity,JiangsuProvince(225266)地址:江苏省江都市丁伙镇(225266)Tel:电话:2.Contentsofproduct产品成分1–ethoxyethanol–2–propylalcohol2–ethoxyethanol–1–propylalcohol1-乙氧基–2-丙醇2–乙氧基–1–丙醇3.Hazardwarningandidentificationmark危险警告,识别标记Summaryofemergencycondition紧急情况综述Itisacolorlessliquidwithetherealodor.Itstimulateseyes,andiscombustible.Itispotentiallyharmfultohealth.(SeePart11forthetoxicitymaterial)无色液体,有醚的气味,会刺激眼睛,易燃。潜在的健康危害(毒性资料见第11部分)Eyes:Itlightlystimulatestheeyesandcornea.Itsvapormayhurttheeyes.眼睛:可轻微刺激眼睛、角膜、蒸汽可能会伤害眼睛。Skin:Long-termorseveraltimes’contactmaystimulateorevenhurttheskin.皮肤:长期或多次接触可引起皮肤刺激,甚至伤害。Takeit:Itstoxicityisverylowifonetakesitonce.Innormaltreatmentcondition,itisnotlikelyharmfultohealthtotakeasmallamountbymistake.However,itispossiblyharmfulifonetakesanoverdoseofit.食入:单一次口服的毒性极低。在正常处理情况下,小量的误食是不大可能导致伤害的,但吞食超过量仍可造成伤害。Inhalation:Asingleinhalationrevealsnoharmfuleffect.吸入:单一吸入暴露无不良影响。Effecttohealth:Theresearchonanimalindicatesthatrepeatedexposuretoithasnoharmfuleffect.影响身体的效应:在对动物的研究中,重复暴露没有不利结果。Teratology(birthdefect):Itdoesnotlikelycausebirthdefect.Themother’sbodyincontactwithitdoesnotbringanysideeffect,andithasnoeffecttofetus.1畸胎学(出生缺陷):不大可能导致出生缺陷。对母体无副效应的接触,不影响胎儿。Effecttobreeding:Theresearchonanimalshowthatitdoesnotdisturbbreeding.对繁殖的影响:在对动物的研究中,不显示干扰繁殖。4.Methodofemergencytreatment急救方法Eyes:Useplentyofclearwatertoscourtheeyes.眼睛:用大量清水冲洗眼睛。Skin:Flushtheskinortakeashower.皮肤:冲水或淋浴洗去。Takeit:Immediatelyseethedoctorifonetakesitbymistake.Donoturgetovomitunlessunderthedirectionofmedicalstaff.食入:如有误吞,立即就医。除非在医护人员的指引下,否则不可催吐。Inhalation:Movetheinjuredpersontotheplacewithfreshairandconsultthephysician.吸入:把伤者移至清新空气处,并咨询内科医生。5.Measuresoffirecontrol消防措施Combustibility可燃性Flashingpoint:42℃闪点:42℃Naturaltemperature:---自然温度:---Combustionlimit(volumepercentage)燃烧极限(体积白分化)Lowerlimit:---下限:---Upperlimit:---上限:---Harmfulproductofburning:Inthefirescene,thesmokemaycontainsoriginalsubstance,andundeterminedtoxicorstimuluscompounds.有害的燃烧产物:在火场中,烟雾可能含有原来物质及不确定的有毒和/或刺激性化合物。Fireextinguishingmedium:waterfogorspray,carbondioxide,extinguishantdrypowder,andfoam.Thewaterfogspraycancoverandextinguishthefire.You’dbetterusethealcoholresistantfoamextinguishant(ATCAype),ifanyavailable.Theartificialsyntheticfoam(includingAFFFTYPB)forgeneraluseortheproteinfoammaybeuseful,buthasaninferioreffect.灭火介质:水雾或洒水、二氧化碳、灭火乾粉、泡沫、喷洒水雾,可用作覆盖火焰,并把它扑灭。如果有的话,最好使用抗醇型灭火泡沫(ATCAype),普通用途的人工合成泡沫(包括AFFFTYPB)或蛋白质泡沫可能会有用,但效果较差。Avoidanceofsubstance:Itisnotallowedtopourwaterdirectly.避免物质:不可直接注水。Directionsforfireextinguishment:Dispersepeoplefromthefirescene,andisolatethesceneandforbidunnecessarypeoplefromentering.Flushwatertoremovetheburningliquidandprotectthepeopleandreducethelossesofproperties.Usewatertodilutetheburningliquidanditcanpossiblystampoutthefireandavoidconcentration.Thisproductmaybedispersedonwatersurfacetohavethefireextendorcontactthefiresource.Spraywatertocooldownthecontainersandtheaffectedzoneinthefiresceneuntiltheflameisextinguished,withoutthedangerofafter-combustion.Immediatelyretreatallthepeopletoavoidthenoisegivenoutingasexhaustionfromthesafetyfacilityortheaffectionofthecontainerfading.Thefiresourceisremoved.Stayintheupwindposition.Keepfarfromthelow-lyingplacewheregas(smoke)maygathers.Youmustnotdirectlypourwater,whichmayleadtotheextensionoffire.Itisuselesstousewaterinfireextinguishment.2Removethecontainersoutofthefiresceneundertheconditionofhavingnodangerinit.灭火指示:疏散人员远离火场。隔离火场及禁止不必要的人进入。冲水可移走燃烧的液体,以保护人员及减低财务损失。用水稀释燃烧中的液体,可能将火扑灭,避免积聚。本产品会分散于水面,可使火势蔓延或接触火源。喷洒水以冷却火场中的容器及受影响的地带,直至火焰熄灭,无复燃的危险。立即撤走所有人员,以避免安全设施于排气时的噪音或容器退色所造成的影响。去除火源。处于上风位置。远离会积聚气体(烟雾)的低洼地带。切勿直接注水因其可能造成火势蔓延。用水救火会没有效用。在没有危险的情况下,把容器移离火场。Protectiveapparatusoffirefighters:Usepositivepressureself-containedbreathingapparatus(SCBA)andwearfirefightingprotectiveapparatus(includinghelmet,clothsandgloves).Ifhavingnoavailableornotusingtheprotectiveapparatus,theyshouldattendthefirefightingintheprotectedzoneorkeepasafetydistance.消防员保护设备:使用正压自携式呼吸器(SCBA)和穿着救火保护装备(包括头盔、衣服、靴和手套),如果没有保护设备可供使用或没有使用保护设备,应在所保护的区域内或在安全距离处救火。7.Productmanagementandstorage产品管理和贮存Productmanagement:Thecontainermaycontainsvapor,evenifthematerialinitispouredout.Donotcutoff,drillholeon,crush,orweldtheemptyornearlyemptycontainerordosimilaroperation.Smoking,ignitionorexistenceofanyfiresourceisstrictlyforbiddenintheplaceofproductmanagementandstorage.Mustnotuseairpressuretotransporttheproduct.Allthetoolsshouldbegrounded.产品管理:即便容器内的材料已倒出,仍可能含有蒸气,不可把空的容器或差不多空的容器剪断、钻孔、压碎、烧焊或进行相类似的操作。在产品管理及贮存的地方,严禁吸烟、点火及任何火源的存在;切勿用空气压力输送产品;所有工具皆应接地。Storage:Itisdetermineddependingontheoperatingstatus.Youcanusesparklessorexplosionprooftools.Ifstaticelectricityisconcentrated,orthereisahotsparkoranopenfire,reducefiresourceasmuchaspossible.Thecontainershouldbefastenedifitisnotused.Usecarbonsteel,stainlesssteelorpolytetrafluoroethylenresincontainertostoretheproduct.贮存:依据操作状况而定,可能使用无火花型或防爆型工具。尽量减少火源,如静电的积聚,热火花及明火。不使用时,应把容器栓紧。贮存容器应使用碳钢、不锈钢或聚四氯乙烯的容器。8.Managementafterproductexposureandpersonalprotectionmeasures产品曝露后的管理和个人保护措施Engineeringcontrol:Airexhaustionmaybepartiallynecessaryforsomeoperations.工程控制:对某些操作,则可能需要局部抽风。Personalprotectionapparatus个人保护设备Eye/faceprotection:Usesafetyglasses.眼/面的保护:使用安全眼镜Skinprotection:Wearcleanclothswithlong-sleeves,whichcancoverthebody.Putonglovescapableofpreventingpermeationoftheproduct,ifcontactingitforalongtimeorconstantly.皮肤保护:穿着洁净、长袖、覆盖身体的衣服。如果长时间或经常地接触,使用能阻挡本产品渗透的手套。Protectionofrespiratorysystem:Theconcentrationofhazardoussubstanceinairmaybeabovethelimitvalueforcontact,oritmakespeoplefeeluncomfortable.Atthistimeyoucanusetherecognizablerespiratortopurifytheair.呼吸道保护:空气中有害物的浓度可能高于接触限值或令人不适,可使用认可的净化空3气式呼吸器。9.PhysicalandchemicalpropertiesAppearance:colorlessliquid物理与化学性质外观:无色液体。Odor:slightethericodorVaporpressure:4.4mmhg@20℃气味:略带醚的气味蒸气压:4.4毫米汞柱@20℃Vapordensity:---Boilingpoint:133℃蒸气密度:----沸点:133℃Dissolvabilityinwater:unlimitedSpecificgravity:0.895@25/25℃水中的溶解度:无限比重:0.895@25/25℃10.Stabilityandchemicalactivereaction稳定性及化学活性反应Chemicalstability:Thestorageunderthesuggestedconditionisstable.Refertothestoragepart.化学稳定性:在建议的条件下贮存是稳定的。参阅贮存部分。Avoidance:Avoidproducingsparkstaticelectricity.Itmayreleasecombustiblevaporinhightemperature.应避免的情况:避免产生火花的静电。高温时会释放出可燃蒸气。Incompatibilitywithothermaterials:Avoidcontactwithoxidant.与其他材料的不相容性:避免与氧化剂接触。Hazardousproductofdissolution:Innormalcondition,itdoesnotdissolve.Therearesomedifferenthazardousproductsofdissolution,dependingonthetemperature,airvolumeandtheexistenceofothersubstances.有害的分解产物:正常情况下不会分解。依温度,空气量和其他物质的存在会有不同的有害分解产物。Hazardouspolyreaction:Itwillnotoccur.危险的聚合反应:不会发生。11.Toxicitymaterial(SeePartIIIconcerningthepotentialaffectiononhealth.)毒性资料(潜在的健康影响参见第三部分)Temporarilyunavailable暂缺12.Ecologicalmaterial(temporarilyunavailable)生态资料(暂缺)413.Pointsforattentionondiscard(SeePart15fortheregulatorymaterial.)弃置须知(法规资料见第15部分)Discard:Itcannotbepouredintoanysewer,ontotheground,orintoanywaterbody.Observethestate,provincial/municipalandlocalregulationsonthedisposalmethods.Theregulationsmayvarydependingonlocality.Itistheresponsibilityofthewasteproducertohandlethewasteinaccordancewiththepropertiesofthewasteandwiththeregulations.Theuseandthemanagementmethodofthisproductintheprocessofmanufacturingisnotunderthecontrolofthiscompany.ThismaterialisapplicableonlywhenitconcernstheloadingandtransportationconditionasrelatedinPartII(componentsoftheproduct)MSDS.Fortheproductthatisnotusedorpolluted,theidealmethodofwastedisposalistosendtheproducttotherecoverystationwithpermit,ortotheincineratororotherheatdecompositionfacility.弃置:不可倒入任何下水道,地面或任何水体。所有处理方法需遵守国家、省/市和地方的法规。法规可能会因地而异。按废弃物特性及附合法规处理,是废料产生者的责任。此产品在制造过程中被使用/及其管理方法,并不在我公司控制下,只有当产品如MSDS于第二部分(产品成分资料)所述及装运时的情况,此资料方可适用。对未使用过,未被污染的产品,理想的废料处理方法包括产品送到领有许可证的回收站,焚化炉及其他热分解设施。14.TransportationMaterial运输资料UnitedStatesDepartmentofTransportation(DOT):美国运输部(D.O.T):Refertothetransportationregulationsandtheproductloadingandtransportationform,ifyouneedDOTregulatorymaterial.如需DOT法规资料,可参阅运输法规,产品装运表格。CanadianTDGmaterial:加拿大TDG资料:Refertothetransportationregulationsandtheproductloadingandtransportationform,ifyouneedTDGregulatorymaterial.如需TDG资料,可参阅运输法规,产品装运表格。15.Regulatorymaterials法规资料Attention:Thematerialsareprovidedinthisformoutofhonesty.Itisbelievedthattheabovementionedvaliddateisaccurate.However,itdoesnotexpressorimplyanyguarantee.Theregulatoryrequirementmaychangeordifferdependingonlocality.Itisthebuyer’sresponsibilitytoguaranteeobservationofthestate,provincial/municipalandlocallawsandregulationsinactivities.Thespecialmaterialsgivenbelowareforfollowingthestate,provincial/municipalandlocallawsandregulations.注意:此表提供的资料是出于诚信,并相信在上述的生效日期时是准确的,但并没有表示或隐含任何保证。法规要求会发生改变,也可能会因地而异。保证其活动遵从国家、省/市和地方的法规是买方的责任。下面的特定的资料是为了遵从一些国家、省/市和地方的法规。U.S.lawsandregulations:美国法规CategoryofSARAhazardousmaterials:Thisproductisexaminedinaccordancewiththe“categoryofhazardousmaterials”ofEPA(EnvironmentalProtectionAgency)in311and312ofTitleIIIofSARA(SuperFundAmendmentsandReauthorizationAct)in1986.Undertheapplicabledefinition,thisproductbelongstothefollowingcategory:SARA危险物类别:本产品已根据1986年SuperFundAmendmentsandReauthorizationAct(SARATitleIII)的311与312部分所公布的EPA“危险物类别”予以审察。在适用定义5下,本产品属于下列分类:ImmediatehazardtohealthFirehazard即时健康危害火警危害ToxicSubstanceControlAct(TSCA)毒性物质控制法案(TSCA)AllthecomponentsaregiveninthelistofTSCA,orarenotrequiredtobeinthelistofTSCA.所有的成分均在TSCA清单上或不被要求列于TSCA清单上。CAScodeofTSCAlist:0052128-53-8在TSCA清单上的CAS号码:0052128-53-8OSHAhazardcommunicationstandard:OSHA危险通讯标准Thisproductisdefinedas“hazardouschemical”inaccordancewith29CFR1910.1200,OSHA(OccupationalSafetyandHealthAdministration)“hazardcommunicationstandard”.本产品被29CFR1910.1200,OSHA“危险通讯标准”定为“危险化学品”Canadianregulations加拿大法规WHMIS(WorkplaceHazardousMaterialsInformationSystem)material:Thisproductisclassifiedasthefollowing,inaccordancewithCanadianWHMIS:WHMIS资料:加拿大工作场地危险材料系统(WHMIS)对本产品的分类为:B2–flashingpointbetween37.8℃and-93.3℃.B2-闪点介于37.8℃-93.3℃之间D2B–stimulustoeyesandskin.D2B-眼镜和皮肤的刺激物Refertootherpartoftheformofthismaterialandtotheeducationalplanoftheoperatingsiteoftheemployer,concerningspecialwarningandsafetyoperationmaterial.特别警告和安全操作资料,参见本资料表的其他部分,并参考雇主的工作场所教育计划。CPRdeclaration:ThisproductisclassifiedinaccordancewiththehazardevaluationstandardofCanadiancontrolledproductregulation(CPR)CPR声明:本产品已根据加拿大受管制产品规章(CPR)的危害评核标准分类。Materialofhazardousmaterialregulation:Thisproductcontainsthefollowingcomponents,whicharelistedasthehazardousmaterialand/orinthepublicizedlistofcomponents(Part13andPart14ofCanadianHPA)危险品法案资料:本产品含有以下成分,而这些成分被列为危险产品和/或被列于成份公开清单上(加拿大HPA第13和14部分)16.Othermaterial其他资料None无6',)
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